您的位置:首頁 > 新聞中心 > 什么?你還停留在制備石墨烯的階段?

什么?你還停留在制備石墨烯的階段?
2016.09.26 點擊8340次
石墨烯是目前世界上最薄卻也是最堅硬的納米材料,它是由單層碳原子構成的蜂窩狀二維晶體,具有優異的電學、熱傳導、阻隔性等材料性能,被稱為“黑金”和“新材料之王”?茖W家曾預言“石墨烯將徹底改變21世紀”。

雖然榮獲2010年諾貝爾獎的兩位科學家僅憑借一卷膠帶、一支鉛筆就制備出了石墨烯,但這并不代表石墨烯就能很快被大規模生產。事實上受技術所限,要大量制得質量高、缺陷少、性能優異的石墨烯絕非易事。
當前石墨烯的制備技術主要包括:化學氣相沉積法,氧化還原法,微機械剝離法和外延生長法等。氧化還原因為操作簡單、制備成本低,產率高等優點已成為實驗室的石墨烯主流合成方法。具體操作過程為:先用強氧化劑濃硫酸、濃硝酸、高錳酸鉀等將石墨氧化成氧化石墨,氧化過程即在石墨層間穿插一些含氧官能團,從而加大了石墨層間距,然后經超聲處理一段時間之后,就可形成單層或數層氧化石墨烯,再用強還原劑水合肼、硼氫化鈉等將氧化石墨烯還原成石墨烯。
|
| 氧化石墨烯制備流程(來源:材料+) |
氧化還原法看似簡單,要注意的地方其實有很多,比如:氧化劑的濃度要合適,反應時間要控制,各種參數要調控等。操作上也需倍加小心,且不說實驗中用到的強氧化劑腐蝕性高,在將這些強氧化劑混合時尤其要注意用量和比例,超出限制很可能引發爆炸。
所以說,制備石墨烯的過程也算是經歷九九八十一難,才能得到理想的產物?上Ъ幢隳阋宦放,操作得當,有時候實驗還是會以失敗告終。
Sigma-Aldrich可以提供多種形式的石墨烯和氧化石墨烯產品,有膜、有粉末、有水溶液。
| Graphene Films | |
| 產品編號 | 產品描述 |
| 3092685 | Graphene field effect transistor chip |
| 3092695 | Graphene nanoribbons alkyl functionalized |
| 3092696 | Graphene nanoribbons |
| 3154816 | Monolayer graphene film, 1 cm x 1 cm on copper foil |
| 3154817 | Monolayer graphene film, 1 cm x 1 cm on quartz |
| 3154818 | Monolayer graphene film, 1 cm x 1 cm on SiO2/Si substrate |
| 3154819 | Monolayer graphene film, 1 in x 1 in on copper foil |
| 3154820 | Monolayer graphene film, 1 in. x 1 in. on PET film |
| 3154821 | Monolayer graphene film, 2 in. x 2 in. on PET film |
| 3246098 | Suspended monolayer graphene on TEM grid substrate (Quantifoil gold) |
| Graphene Ink | |
| 產品編號 | 產品描述 |
| 3092681 | Graphene dispersion with ethyl cellulose in cyclohexanone and terpineol, inkjet printable |
| 3092682 | Graphene dispersion 10 mg/mL, dispersion in NMP |
| 3092683 | Graphene dispersion with ethyl cellulose in terpineol, gravure printable |
| 3092684 | Graphene dispersion with ethyl cellulose in terpineol, screen printable |
| 3092686 | Graphene ink in water flexo/gravure/screen printable |
| 3092687 | Graphene ink in water Inkjet printable |
| 3092688 | Graphene ink in water screen printable |
| 3300565 | 3D Printing Graphene Ink |
| Graphene Oxide | |
| 產品編號 | 產品描述 |
| 3092697 | Graphene oxide 2 mg/mL, dispersion in H2O |
| 3092698 | Graphene oxide sheets |
| 3092699 | Graphene oxide 4 mg/mL, dispersion in H2O |
| 3092700 | Graphene oxide 15-20 sheets, 4-10% edge-oxidized, 1 mg/mL, dispersion in H2O |
| 3092701 | Graphene oxide powder, 15-20 sheets, 4-10% edge-oxidized |
| 3092703 | Graphene oxide, alkylamine functionalized 2.0 mg/mL, dispersion (in toluene) |
| 3092704 | Graphene oxide, ammonia functionalized 1 mg/mL, dispersion in H2O |
| 3092702 | Graphene oxide nanocolloids 2 mg/mL, dispersion in H2O |
| Graphene Powder and Dispersion | |
| 產品編號 | 產品描述 |
| 3092689 | Graphene nanoplatelets powder |
| 3092690 | Graphene nanoplatelets 1 mg/mL, dispersion in H2O |
| 3092691 | Graphene nanoplatelets powder, polycarboxylate functionalized, hydrophilic |
| 3092692 | Graphene nanoplatelets powder, hydrocarbon functionalized, hydrophobic |
| 3092693 | Graphene nanoplatelets powder, oxidized |
| 3092694 | Graphene nanoplatelets powder, hydrophobic |
| Nanocomposites | |
| 產品編號 | 產品描述 |
| 3086884 | Fe3O4/graphene nanocomposite 10 mg/mL, dispersion in acetone |
| 3086885 | Fe3O4/reduced graphene oxide nanocomposite 10 mg/mL, dispersion in acetone |
| 3139211 | Mn3O4/graphene nanocomposite 10 mg/mL, dispersion in acetone |
| 3139212 | Mn3O4/reduced graphene oxide nanocomposite 10 mg/mL, dispersion in acetone |
| 3179595 | Pd/graphene nanocomposite 10 mg/mL, dispersion in acetone |
| 3179596 | Pd/reduced graphene oxide nanocomposite 10 mg/mL, dispersion in acetone |
| 3210716 | PtCo/graphene nanocomposite 10 mg/mL, dispersion in acetone |
| 3210717 | PtCo/reduced graphene oxide nanocomposite 10 mg/mL, dispersion in acetone |
| 3210891 | PtPd/graphene nanocomposite 10 mg/mL, dispersion in acetone |
| 3210892 | PtPd/reduced graphene oxide nanocomposite 10 mg/mL, dispersion in acetone |
| 3210691 | Pt/reduced graphene oxide nanocomposite 10 mg/mL, dispersion in acetone |
| 3252749 | TiO2/graphene nanocomposite 10 mg/mL, dispersion (in acetone) |
| Reduced Graphene Oxide | |
| 產品編號 | 產品描述 |
| 3214706 | Reduced graphene oxide |
| 3214707 | Reduced graphene oxide |
| 3214708 | Reduced graphene oxide amine functionalized |
| 3214709 | Reduced graphene oxide octadecylamine functionalized |
| 3214710 | Reduced graphene oxide tetraethylene pentamine functionalized |
| 3214711 | Reduced graphene oxide piperazine functionalized |





